There's a few theories about the best way to harvest your buds, including keeping them in up to 72 hours of darkness before the actual chop. But is it all nonsense?
Thrichomes containing THC, among all the other cannabinoids, are believed to be produced as the plants way to protect itself from the effects of harmful UV radiation from the sun and other mildly stressful environmental factors. Suddenly turning off the sun for a few days is said to increase THC due to a stress response.
Another theory is that it evolved from the plants need to pollinate before winter. As the nights grow shorter, the plants produce more and more trichome covered buds in the hope of being pollinated and producing seeds. This doesn't make sense as no one can switch off the sun for days at a time in order for this evolution to happen.
Finally, the theory that makes most sense to me, is that cannabinoid levels fluctuate over 24 hours. They peak just at the end of the dark period and are degraded during the day as they protect the plant from UV radiation. During the night, the plants replenish the degraded trichomes ready for the next day. By extending the dark period, the plants should be producing more cannabinoids than normal.
I can't actually find the scientific papers that prove any theory but the story goes that there were experiments carried out by the Stichting Institute of Medical Marijuana (SIMM). In the experiment they harvested half of their plants as normal, and kept the other half in darkness for 72 hours. When they later analyzed the final crop, the THC level in some of the strains was up as much as 30% compared to the buds harvested normally.
The same is also true for Terpines. During the day, these evaporate and are replenished during the night cycle. These are what make your plants smell amazing and also add to the entourage effect. After 48 hours in darkness, your plants REALLY begin to smell, and this is why.
If you're in a rush, the best time to harvest is right before the lights are due to come on. This ensures no cannabinoids have been degraded yet.
You'll barely notice any difference after 24 hours darkness either as the process has only just started to elevate but you can do it for 48 - 72 hours and get good results. Some people claim they've done it for up to a week before, but I haven't tried this at all.
Just remember that the longer you leave it... The less solid your buds become.
If you're going to try this... Make sure you don't water your plants so the soil or coco is dry before you do. Lower humidity = more THC and high levels of moisture in the air or ground can lead to Mould and the dreaded bud rot!
Have you tried this? Do you swear by it? What were your results? I do it every time although I don't remember if it does make things better, it just makes a lot of sense to me to do it this way.